Product name: 2-(Tributylstannyl)furan
CAS Number:118486-94-5
Molecular Weight: 357.12
Molecular Formula:C16H30OSn
MDL numbering:MFCD00192512
Use of 2-(Tributylstannyl)furan:
2-(tributyl tin alkyl)furan is a tributyltin derivative, which can be used to synthesize many tributyltin carboxylate and tributyltin dithiophosphonate organotin compounds with biological activities such as insecticide, bactericidal and herbicidal control, and is a promising new pesticide intermediate.
preparation of 2-(Tributylstannyl)furan:
Tributyltin chloride was weighed, refluxed and stirred in 30mL furan for 10h. Filtration, the filtrate is concentrated to an appropriate volume under reduced pressure, 3mL~5mL petroleum ether is added, it is allowed to stand at low temperature, filtered after the precipitation is complete, and the crude product is recrystallized with dichloromethane-petroleum ether. After removing the solvent, it was repeatedly washed and purified with petroleum ether to obtain a colorless viscous liquid 2-(tributyl stankyl) furan.
Chemical & Physical Properties
Boiling Point |
90 °C0.1 mm Hg(lit.) |
Density |
1.134 g/mL at 25 °C(lit.) |
Index of Refraction |
n20/D 1.494(lit.) |
Flash Point | >230 °F |
Storage conditions |
Inert atmosphere,Room Temperature |
morphology |
liquid |
specific gravity |
1.134 |
| Hydrolysis susceptibility
|
4: no reaction with water under neutral conditions
|
Safety Information
Hazard Symbol (GHS) | GHS06,GHS08,GHS09 |
Warning words | Dangerous |
Hazard description | H301-H312-H315-H319-H360FD-H372-H410 |
Precautionary Statement | P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338 |
Hazard Goods Signs | T,N |
Hazard Category Code | R21-R25-R36/38-R48/23/25-R50/53 |
Safety instructions | S35-S36/37/39-S45-S60-S61
|
Dangerous goods shipping number | UN 2788 6.1/PG 3 |
WGK Germany
| 3
|
F
| 10
|
TSCA
| NO
|
| Hazard Rating | 6.1(b) |
| Packaging category | Ⅲ |
| HS Code | 29321900
|